2-methyl-3(2h)-isot...

2-methyl-3(2h)-isothiazolon

2-methyl-3(2h)-isothiazolon

Min.Order / FOB Price:Get Latest Price

1 Metric Ton

Negotiable

  • Min.Order :1 Metric Ton
  • Purity: 15
  • Payment Terms : L/C,D/A,D/P,T/T,Other

Keywords

Skycide 100 Methylisothiazolinone Isothiazolone,2-methyl-

Quick Details

  • Appearance:Liquid
  • Application:Bactericide
  • PackAge:200kg drum
  • ProductionCapacity:100000|Metric Ton|Month
  • Storage:Dry cool clean warehouse
  • Transportation:By sea or air

Superiority:

2-Methyl-4-isothiazolin-3-one

  • CAS:2682-20-4
  • CBNumber:CB0193926
  • MF:C4H5NOS
  • MW:115.15

SAFETY DATA SHEETS

 

According to the UN GHS revision 10

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1GHS Product identifier

Product name

2-methyl-2H-isothiazol-3-one

1.2Other means of identification

Product number

-

Other names

methylisothiazolin-3-one;MIT;METHYLISOTHIAZDINONE

1.3Recommended use of the chemical and restrictions on use

Identified uses

Industrial and scientific research use.

Uses advised against

no data available

 

SECTION 2: Hazard identification

 

2.1Classification of the substance or mixture

Acute toxicity - Category 3, Oral

Acute toxicity - Category 3, Dermal

Skin corrosion, Sub-category 1B

Serious eye damage, Category 1

Skin sensitization, Sub-category 1A

Acute toxicity - Category 2, Inhalation

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

2.2GHS label elements, including precautionary statements

Pictogram(s)   
Signal word

Danger

Hazard statement(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H314 Causes severe skin burns and eye damage

H317 May cause an allergic skin reaction

H330 Fatal if inhaled

H410 Very toxic to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P271 Use only outdoors or in a well-ventilated area.

P284 [In case of inadequate ventilation] wear respiratory protection.

P273 Avoid release to the environment.

Response

P301+P316 IF SWALLOWED: Get emergency medical help immediately.

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P316 Get emergency medical help immediately.

P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P363 Wash contaminated clothing before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P317 Get medical help.

P333+P317 If skin irritation or rash occurs: Get medical help.

P362+P364 Take off contaminated clothing and wash it before reuse.

P320 Specific treatment is urgent (see ... on this label).

P391 Collect spillage.

Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

2.3Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1Substances

Chemical name Common names and synonyms CAS number EC number Concentration
2-methyl-2H-isothiazol-3-one 2-methyl-2H-isothiazol-3-one 2682-20-4 220-239-6 100%

SECTION 4: First-aid measures

4.1Description of necessary first-aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

4.2Most important symptoms/effects, acute and delayed

no data available

4.3Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Poisons A and B

SECTION 5: Fire-fighting measures

5.1Suitable extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.

5.2Specific hazards arising from the chemical

no data available

5.3Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.

6.2Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3Methods and materials for containment and cleaning up

Accidental Release Measures. Personal precautions: Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

SECTION 7: Handling and storage

7.1Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

SECTION 8: Exposure controls/personal protection

8.1Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state

Liquid

Colour

Colorless prisms

Odour

no data available

Melting point/freezing point

254-256°C

Boiling point or initial boiling point and boiling range

182.8°C at 760 mmHg

Flammability

no data available

Lower and upper explosion limit/flammability limit

no data available

Flash point

64.3°C

Auto-ignition temperature

no data available

Decomposition temperature

no data available

pH

no data available

Kinematic viscosity

no data available

Solubility

In water, 5.367X10+5 mg/L at 25 deg C (est)

Partition coefficient n-octanol/water

log Kow = -0.83 (est)

Vapour pressure

<0.1 mm Hg ( 25 °C)

Density and/or relative density

1.25 (14% aq.)

Relative vapour density

no data available

Particle characteristics

no data available

SECTION 10: Stability and reactivity

10.1Reactivity

no data available

10.2Chemical stability

Stable under recommended storage conditions.

10.3Possibility of hazardous reactions

no data available

10.4Conditions to avoid

no data available

10.5Incompatible materials

Materials to avoid: Strong oxidizing agents, Amines, Mercaptans, Reducing agents.

10.6Hazardous decomposition products

When heated to decomposition it emits toxic vapors of SOx.

SECTION 11: Toxicological information

Acute toxicity

  • Oral: LD50 Rats(female) oral 183 mg/kg bw RH-573 Technical
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

SECTION 12: Ecological information

12.1Toxicity

  • Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill) weight 0.58 g; Conditions: freshwater, flow through; Concentration: 300 ug/L for 96 hr (95% confidence interval: 240-320 ug/L) /14.17% purity
  • Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, flow through; Concentration: 180 ug/L for 48 hr (95% confidence interval: 140-190 ug/L); Effect: intoxication, immobilization /14.17% purity
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2Persistence and degradability

AEROBIC: Utilizing a CO2 evolution test with a freshly prepared activated sludge inoculum, methylisothiazolinone reached 54.1, 55.8 and 47.6% CO2 evolution, at initial concentrations of 0.3, 0.03 and 0.01 ppm, respectively, over a 28 day incubation period; the results classified the compound as inherently biodegradable and demonstrated a dependence on concentration. Microcosm studies in aerobic water found degradation of methylisothiazolinone to be primarily due to biodegradation based on tests using sterile controls. The half-life of methylisothiazolinone in an aerobic microcosm using river water and sediment was 9 days(1).

12.3Bioaccumulative potential

A BCF of 3 was reported in bluegill sunfish (Lepomis macrochirus) for methylisothiazolinone(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of methylisothiazolinone can be estimated to be 12(SRC). According to a classification scheme(2), this estimated Koc value suggests that methylisothiazolinone is expected to have very high mobility in soil.

12.5Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1UN Number

ADR/RID: no data available IMDG: no data available IATA: no data available

14.2UN Proper Shipping Name

ADR/RID: no data available IMDG: no data available IATA: no data available

14.3Transport hazard class(es)

ADR/RID: 6.1 (For reference only, please check.) IMDG: 6.1 (For reference only, please check.) IATA: 6.1 (For reference only, please check.)

14.4Packing group, if applicable

ADR/RID: III (For reference only, please check.) IMDG: III (For reference only, please check.) IATA: III (For reference only, please check.)

14.5Environmental hazards

ADR/RID: Yes IMDG: Yes IATA: Yes

14.6Special precautions for user

no data available

14.7Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
2-methyl-2H-isothiazol-3-one 2-methyl-2H-isothiazol-3-one 2682-20-4 220-239-6
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.
Korea Existing Chemicals List (KECL) Listed.

SECTION 16: Other information

Information on revision

Creation Date July 15, 2019
Revision Date July 15, 2019

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

Package&Shipping

Details:

Qingdao Bravery International Trading Co., LTD. is located in the beautiful tourist city of Qingdao, is a comprehensive chemical enterprise which doing import and export business. Product range including, API, pharmacy intermediates,food additive,Surfactant ,fungicides and other general chemicals. etc.

With the developing world market, we adhere to the principle of "quality, service, integrity and development" ,Forge ahead,and constantly in pursuit of higher level of product quality and service.

We warmly welcome customers home and abroad to build mutual trust, mutual benefit and stable cooperation relation.

 

General items: import and export of goods; Technology import and export; Food additive sales; Feed additive sales; Sales of special chemical products (without hazardous chemicals); Sales of chemical products (excluding licensed chemical products); Livestock and fishery feed sales; Feed raw material sales; Fertilizer sales; Sales of bio-based materials; Health food (pre-packaged) sales; Food sales (pre-packaged food only); Sales of agricultural and sideline products; Pharmaceutical excipients sales; Drug wholesale

 

 

We could give you:

1.Best quality in your requirement

2.Competitive price in China market with standard high quality or customize

3.mature Technical support,Well-trained and professional technologist and sales with rich experience in the field for 5-10 years

4.Professional logistic support,Free sample and correct shipping documents dispatched according to regulations of different countries

All we want is win-win business. Send your inquiries, you will get it!

 

Why choose us:

1.Factory direct sales, so we can provide the competitive price and high quality product base on 5 years of production and R&D experience

2.It is available in stock for quick shipment. Products could be packaged according to customer’s specialized requirements.

3.The products can be transported by Courier, air or sea.

4.Customers will receive the most professional technical support and efficient service.

5.Any inquiries will be replied within 24hours.

6.High purity with test report.

Related Searches

Confirm to collect the product to my collection?

OKCancel

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View